Help with Adobe Photoshop CS2 for Mac?

Riddles    Photoshop CS2     Adobe, HELP, photoshop

I am trying to adjust my hair color, and have followed several tutorials that give me the exact same steps when about new layers and adjusting the hue/saturation etc. However, whenever I trying using the brush either nothing happens or the program complains that the layer is locked, even though I already unlocked it. Is there some setting or option that I am missing here? If it helps, the image I am using I first edited in iPhoto and is saved as a .png file, and then I opened it in photoshop and went to image-> mode and changed it to CYMK. Any help? Thanks

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